The situation is tricky, but it's not impossible. The fact that you didn't see the sign by itself isn't an argument that'll hold up in court, like they said, because drivers are obliged to know the speed limits in school zones - that's in the law and the signage could've been there for years. However, if you can prove that the sign was damaged, covered in vegetation, or genuinely unreadable at that specific moment, then you do have grounds to appeal. Taking a photo of the location now (even if a week has passed) and documenting the condition of the signage helps.
The appeal follows a process: you have 15 business days from the date of notification to file a complaint with the National Road Safety Authority (ANSR). If that doesn't work out, you can then appeal to administrative court. But let's be honest, with 52 km/h in a 40 km/h zone at a school, your margin is thin. The fine will stick even if you appeal, unless you find something concrete about the signage.
Here's the trick nobody mentions: request a detailed report of the location where you got the fine - ANSR has to send you information about exactly where the sign was, what condition it was in, what equipment measured your speed. If there's any inconsistency in that report (for example, if the sign was 50 meters before the curve or if the speed-measuring equipment's calibration was out of date), then you've got arguments. A lot of people don't even know they can ask for this and end up not doing it.