The most reliable test is to touch the stain: if it's cold and damp to the touch while the rest of the ceiling is dry, it's probably condensation. But if it's dry and has a powdery consistency or is slightly sticky even when there's no visible dripping, it's almost certainly mold. Another telltale sign is the smell: mold has that characteristic stale, musty odor, while condensation doesn't smell.
In my case I had both things happening at the same time in my bathroom - condensation on the window but also mold in the ceiling corners. The condensation would disappear when I turned on the fan, while the mold came back within a week even after I cleaned and dried everything thoroughly. The difference is that condensation is a symptom of humid air (poor air circulation, temperatures too low), while mold indicates that the humidity has already created conditions for biological growth - in other words, the damage goes deeper.
In your case, since it's always in the same corner near the window, I'd say it could be a combination of both. Try cleaning thoroughly with a solution of water and vinegar (you don't need bleach on all surfaces), dry everything, and then monitor it: if it comes back quickly in the same spot after a week, it's real mold and there could be a water leak or an infiltration from the window, so yeah, it's worth having someone who knows what they're doing take a look at it. If it stays dry for weeks, it's probably just a matter of better ventilation in the room.