Don't decide based just on the range figures the manufacturers advertise - that data is measured in a lab under nearly perfect conditions, and in winter you easily lose 20-30% depending on your region and driving style. What really matters is test-driving both for real over a few days, ideally with a mixed route (highway, regular roads, city) and in bad weather if possible.
Between the e-3008 and the ID.5, the Peugeot is generally a bit more comfortable inside and easier to live with day-to-day for urban trips. The VW offers better energy efficiency over long distances and slightly faster charging. But honestly, if you're coming from a diesel 307, both will feel smooth and quiet to you. The big difference will actually be in the details: Peugeot's touchscreen interface versus VW's, the ergonomics of the controls, how you feel in the driving position.
Here's the thing most people don't do: before you buy, sign up for an electric car-sharing app (Zity, Citiz, whatever exists where you are) and rent a similar model for a full week including a long trip. You'll experience the real constraints - finding a charger, waiting for recharge, seeing how it behaves when the battery gets low. It costs peanuts compared to a bad purchase, and it completely changes your perspective. After that you'll know whether winter range is a real issue for you or just a theoretical worry.