A 3L/100km difference is pretty significant, so before you start panicking you need to check the basics. Are your tires properly inflated? You won't notice an underinflated tire while driving but it eats up fuel for nothing. Also, the way you drive has a huge impact in the city - if you accelerate hard then brake, if you idle too long, it absolutely tanks your consumption. Since you bought your Clio have you changed your routes or your driving habits? These are dumb questions but that's usually where it comes down to.
If it's really a mechanical issue, I'd start with the air filter (a lot of people forget about it), then the spark plugs if they're old. A spark plug that's acting up might not feel dramatic when you're driving, but it changes everything fuel-wise. Are your brakes dragging? Sometimes a caliper that's sticking a little, you barely feel it but that friction is just fuel going up in smoke.
Where people generally don't think to look is the fuel itself - are you switching gas stations? Some low-quality stations sell less energetic fuel or fuel with water in it. It's rare but it happens. Try filling up at a good station (Total, Shell, etc) and do a proper test over 200-300 km before you freak out. And one more dumb thing: are you sure your fuel gauge isn't messing with you? Like it's not rising too high or it's fluctuating? Gauges acting up is more common than you'd think on new cars.