Have you already checked the energy-saving settings in your Samsung's menu, or are you looking more for hardware stuff?
Honestly, Samsung QLEDs have quite a few options to lower power consumption without making it painful to watch. The first thing to do is enable energy-saving mode - not the ultra-aggressive one, just the standard setting. Then turn down the brightness to something reasonable for the afternoon. Like, if your room gets good natural light, you can drop it to 40-50% without really noticing the difference. The real game-changer is disabling useless stuff: the blue LEDs on the control panel, the constant backlighting on the edges, all that. It doesn't consume much individually but it adds up.
Another thing: make sure you don't have something like "motion smoothing" running all the time, because that takes a decent amount of power. And honestly, check your network connection - if your TV is constantly scanning Wi-Fi networks because it's positioned badly, that boosts consumption too. For the afternoon specifically, set a timer or just turn it off completely when you're not actively watching. These 2023 models easily use 80-100W during normal operation, but with adjusted settings you can easily get down to 50-60W.