Condensation buildup in your exhaust system overnight is what's creating that white vapor, and it's completely harmless. When your engine sits unused, moisture from the combustion process condenses inside the cold pipes and muffler. The moment you start up and things heat, that water evaporates back into steam and shoots out the tailpipe - looking like smoke for maybe 30 seconds until the whole system reaches operating temperature. On a 2019 Civic especially, this is textbook normal behavior, particularly in colder climates or during winter mornings.
I had a similar thing happen with my own car years back and it genuinely had me worried until I dug into it. Took it to someone I trust and they just laughed - said every vehicle does this to some degree. The key thing is that it disappears quickly once the engine's warm. If it stuck around for minutes, or got worse as the engine heated up, that'd be a different story and worth investigating. But your timing and pattern match exactly what you'd expect from simple condensation.
The fact that it clears up completely tells you everything's working as designed. Your fuel's burning cleanly, your exhaust isn't leaking, and you don't have coolant mixing into the combustion chamber (which would be a real problem and smell noticeably sweet). Just keep an eye on your oil level now and then - that's the actual maintenance thing worth staying on top of - and you're fine.